Forskning
Our research interests center on the preparation and characterization of new coordination polymers/metal-organic framework with industrially relevant properties in catalysis, adsorption and separation, sensing properties and energy related applications. The research group is also interested in inorganic-organic hybrid materials in general and selected nanoparticle composite materials. The main activity of the research group is within materials discovery and crystal structure determination, characterization of the material’s fundamental chemical properties, and deduction of the corresponding structure-property relationship, frequently with the help of time-resolved synchrotron X-ray diffraction measurements.
Undervisning
Courses
KJEM120 - Grunnstoffenes kjemi
NANO244 - Material- og nanokjemi
Master theses
Master theses are available for a variety of subjects within the topics of materials science the research group is active in. We are very much interested in synthesis of new materials with interesting properties for application in catalysis, adsorption and separation, renewable energy, and as sensors. The most promising materials are characterized more in depth using a variety of methods, like X-ray diffraction (including in-situ experiments performed at a synchrotron), simultaneous thermogravimetric analysis and differential scanning calorimetry coupled to mass spectrometry, and advanced gas and vapor adsorption and chemisorption.
One research focus is on coordination polymers (also known as metal-organic frameworks), which are inorganic-organic hybrid materials. Coordination polymers are interesting in many areas of application. For instance, they frequently have regular pores of <3 to 20 Å (i.e. 0.3-2 nm) which make them interesting materials for adsorption and separation processes, e.g. for CO2 capture or gas and liquid purification. They can also be functionalized to carry catalytic functions or act as sensors.
In addition, we are engaged in research of nanoparticles on supports, e.g. metal supported catalysts. The interest there is to prepare materials with a narrow size distribution of the nanoparticles and investigate the effect on catalytic properties.
Master theses can span quite a wide range from synthesis to advanced characterization of materials. Most theses will contain most of these tasks to a certain extent. However, it is often possible to put the emphasis on the area a student is most interested in. For instance, students who are mainly interested in experimental synthetic work, a thesis subject may be predominantly concerned with discovery of new materials. On the other hand, a thesis can also be geared more towards thorough characterization of a material. The synthetic part of such a thesis will then play a minor part. It will usually consist of preparing an already known compound for in-depth investigation by the various characterization techniques.
Publikasjoner
2020
- Alexander Westbye; Maria Asuncion Aranda Sanchez; Pascal D.C. Dietzel et al. (2020). A calcium zirconate based combined material for calcium-copper chemical looping technology. (ekstern lenke)
- Pascal D.C. Dietzel; Peter A. Georgiev; Morten Frøseth et al. (2020). Effect of larger pore size on the sorption properties of isoreticular metal–organic frameworks with high number of open metal sites. (ekstern lenke)
- Nuşik Gedikoğlu; Mali Husby Rosnes; Pascal D.C. Dietzel (2020). Adsorption of greenhouse gas N2O on microporous CPO-27 materials. (ekstern lenke)
- Breogán Pato-Doldán; Mali Husby Rosnes; Dmitry Chernyshov et al. (2020). Carbon dioxide induced structural phase transition in metal-organic frameworks CPO-27. (ekstern lenke)
2016
- Breogán Pato-Doldán; Mali Husby Rosnes; Pascal D.C. Dietzel (2016). Shining light on the CO2 adsorption process in metal-organic framework CPO-27-M. (ekstern lenke)
- Breogán Pato-Doldán; Mali Husby Rosnes; Pascal D.C. Dietzel (2016). Shining light on the CO2 adsorption process in metal-organic framework CPO-27-M. (ekstern lenke)
- Mali Husby Rosnes; Pascal D.C. Dietzel (2016). In-depth investigations of the formation of metal-organic framework (MOF) materials. (ekstern lenke)
- Breogán Pato-Doldán; Mali Husby Rosnes; Pascal D.C. Dietzel (2016). A Comprehensive Structural Study of the CO2 Adsorption Process in the CPO-27 Family. (ekstern lenke)
- Mali Husby Rosnes; Pascal D.C. Dietzel (2016). In-depth investigations of the formation of functional materials. (ekstern lenke)
- Fredrik Lundvall; David Wragg; Pascal D.C. Dietzel et al. (2016). Two new Cu(II) and La(III) 2D coordination polymers, synthesis and: In situ structural analysis by X-ray diffraction. (ekstern lenke)
- Andrey Bezrukov; Karl Wilhelm Törnroos; Pascal D.C. Dietzel (2016). Variation of desolvation behavior in two isostructural metal–organic frameworks based on a flexible, racemic bifunctional organic linker. (ekstern lenke)
2015
- Andrey Bezrukov; Karl Wilhelm Törnroos; Pascal D.C. Dietzel (2015). Variation in porous coordination polymer structure due to deprotonation level of hydroxyl groups of a flexible bifunctional linker. (ekstern lenke)
- Mali Husby Rosnes; Pascal D.C. Dietzel (2015). In-depth investigations of the formation of metal-organic framework (MOF) materials. (ekstern lenke)
- Andrey Bezrukov; Karl Wilhelm Törnroos; Pascal D.C. Dietzel (2015). Variation in porous coordination polymer structure due to deprotonation level of hydroxyl groups of a flexible bifunctional linker. (ekstern lenke)
- Mali Husby Rosnes; Agnieszka A Gorzkowska-Sobas; Jonatan Claussen DeLange et al. (2015). Novel adsorbents for toxic industrial gases: CPO-27-M (M=Co, Cu, Zn, Mn, Ni, Mg) performance against ammonia. (ekstern lenke)
- Mali Husby Rosnes; Pascal D.C. Dietzel (2015). In-depth investigations of the formation of metal-organic framework (MOF) materials. (ekstern lenke)
2013
- Pascal D.C. Dietzel (2013). MOFs: From gas adsorption to crystal structures. (ekstern lenke)
- Pascal D.C. Dietzel (2013). Structure-property relationships in coordination polymers with open metal sites. (ekstern lenke)
- Pascal D.C. Dietzel (2013). Coordination polymers with open metal sites: From crystal structure to gas adsorption. (ekstern lenke)
- Pascal D.C. Dietzel (2013). Enlarging the honeycomb: Coordination polymers with high concentration of open metal sites. (ekstern lenke)
2017
- Andrey Bezrukov; Karl Wilhelm Törnroos; Pascal D.C. Dietzel (2017). Variation of network dimensionality and adsorption properties of metal-organic frameworks based on a series of phosphine containing linkers. (ekstern lenke)
- Breogán Pato-Doldán; Mali Husby Rosnes; Pascal D.C. Dietzel (2017). An In-Depth Structural Study of the Carbon Dioxide Adsorption Process in the Porous Metal–Organic Frameworks CPO-27-M. (ekstern lenke)
- Pascal D.C. Dietzel (2017). Understanding adsorbent-adsorbate structures and structure-property relationships in metal-organic frameworks from diffraction and physisorption experiments. (ekstern lenke)
- Tim Ahnfeldt; Marc Christoph Enssle; Maria del Prado Carrion-Ramirez et al. (2017). Effect of ligand substitution on breathing mode of MOFs with MIL-53 type crystal structure. (ekstern lenke)
- Fredrik Lundvall; David Wragg; Ponniah Vajeeston et al. (2017). Ab initio structure solution and thermal stability evaluation of a new Ca(II) 3D coordination polymer using synchrotron powder X-ray diffraction data. (ekstern lenke)
- Andrey A. Bezrukov; Karl Wilhelm Törnroos; Pascal D.C. Dietzel (2017). Modification of Network and Pore Dimensionality in Metal–Organic Frameworks Containing a Secondary Phosphine Functionality. (ekstern lenke)
- Breogán Pato-Doldán; Mali Husby Rosnes; Pascal D.C. Dietzel (2017). An in-depth structural study of the CO2 adsorption process in porous metal-organic frameworks CPO-27. (ekstern lenke)
2008
- Pascal Dietzel; Rune Esben Johnsen; R Blom et al. (2008). Structural changes and coordinatively unsaturated metal atoms on dehydration of honeycomb analogous microporous metal-organic frameworks. (ekstern lenke)
- Pascal Daniel Croumbie Dietzel; Rune E. Johnsen; Helmer Fjellvåg et al. (2008). Adsorption properties and structure of CO2 adsorbed on open coordination sites of metal organic Framework Ni2(dhtp) from gas adsorption, IR spectroscopy and X-ray diffraction. (ekstern lenke)
- Pascal Dietzel; Richard Blom; Helmer Fjellvåg (2008). Base-induced formation of two magnesium metal-organic framework compounds with a bifunctional tetratopic ligand. (ekstern lenke)
- JG Vitillo; L Regli; S Chavan et al. (2008). Role of exposed metal sites in hydrogen storage in MOFs. (ekstern lenke)
- F Bonino; S Chavan; JG Vitillo et al. (2008). Local structure of CPO-27-Ni metallorganic framework upon dehydration and coordination of NO. (ekstern lenke)
2014
- Fredrik Lundvall; David Wragg; Pascal D.C. Dietzel et al. (2014). Methyl 5-iodo-2-methoxybenzoate. (ekstern lenke)
- Christian Chmelik; Alexander Mundstock; Pascal D.C. Dietzel et al. (2014). Idiosyncrasies of Co2(dhtp): In situ-annealing by methanol. (ekstern lenke)
- Fredrik Lundvall; David Wragg; Pascal D.C. Dietzel et al. (2014). 4,4′-dimethoxybiphenyl-3,3′-dicarboxylic acid. (ekstern lenke)
- Mali Husby Rosnes; Martin Opitz; Pascal D.C. Dietzel (2014). Utilizing a modulator approach to control the crystallization process of CPO-27-Ni. (ekstern lenke)
2012
- Fredrik Lundvall; David Wragg; Pascal D.C. Dietzel et al. (2012). New MOFs based on the unexplored linker 4,4’-dimethoxy-3,3’-biphenyldicarboxylic acid. (ekstern lenke)
- Pascal D.C. Dietzel; Rune Esben Johnsen; P.A. Georgiev et al. (2012). Identification of preferred adsorption sites in coordination polymers with open metal sites. (ekstern lenke)
- Pascal D.C. Dietzel; Morten Frøseth; Rune Esben Johnsen et al. (2012). An Isoreticular Series of Coordination Polymers with Enlarged Honeycomb Structure and High Concentration of Open Metal Sites. (ekstern lenke)
- Sachin Chavan; Jenny G. Vitillo; Cherif Larabi et al. (2012). Functionalization of CPO-27-Ni through metal hexacarbonyls: The role of open Ni2+ sites. (ekstern lenke)
2025
- Pascal Daniel Croumbie Dietzel (2025). How do we figure out how atoms are connected in compounds?. (ekstern lenke)
- Pascal Daniel Croumbie Dietzel (2025). Medisinsk mirakel og kjemisk magi: Dette er nobelprisvinnerne 2025. (ekstern lenke)
- Julie Brun; Amrita Panigrahi; Pascal Daniel Croumbie Dietzel (2025). Direct observation of the dehydration of a metal hydroxido cluster to a metal oxido cluster in a metal-organic framework. (ekstern lenke)