Forskning
Our research interests center on the preparation and characterization of new coordination polymers/metal-organic framework with industrially relevant properties in catalysis, adsorption and separation, sensing properties and energy related applications. The research group is also interested in inorganic-organic hybrid materials in general and selected nanoparticle composite materials. The main activity of the research group is within materials discovery and crystal structure determination, characterization of the material’s fundamental chemical properties, and deduction of the corresponding structure-property relationship, frequently with the help of time-resolved synchrotron X-ray diffraction measurements.
Undervisning
Courses
KJEM120 - Grunnstoffenes kjemi
NANO244 - Material- og nanokjemi
Master theses
Master theses are available for a variety of subjects within the topics of materials science the research group is active in. We are very much interested in synthesis of new materials with interesting properties for application in catalysis, adsorption and separation, renewable energy, and as sensors. The most promising materials are characterized more in depth using a variety of methods, like X-ray diffraction (including in-situ experiments performed at a synchrotron), simultaneous thermogravimetric analysis and differential scanning calorimetry coupled to mass spectrometry, and advanced gas and vapor adsorption and chemisorption.
One research focus is on coordination polymers (also known as metal-organic frameworks), which are inorganic-organic hybrid materials. Coordination polymers are interesting in many areas of application. For instance, they frequently have regular pores of <3 to 20 Å (i.e. 0.3-2 nm) which make them interesting materials for adsorption and separation processes, e.g. for CO2 capture or gas and liquid purification. They can also be functionalized to carry catalytic functions or act as sensors.
In addition, we are engaged in research of nanoparticles on supports, e.g. metal supported catalysts. The interest there is to prepare materials with a narrow size distribution of the nanoparticles and investigate the effect on catalytic properties.
Master theses can span quite a wide range from synthesis to advanced characterization of materials. Most theses will contain most of these tasks to a certain extent. However, it is often possible to put the emphasis on the area a student is most interested in. For instance, students who are mainly interested in experimental synthetic work, a thesis subject may be predominantly concerned with discovery of new materials. On the other hand, a thesis can also be geared more towards thorough characterization of a material. The synthetic part of such a thesis will then play a minor part. It will usually consist of preparing an already known compound for in-depth investigation by the various characterization techniques.
Publikasjoner
2020
- Alexander Westbye; Maria Asuncion Aranda Sanchez; Pascal D.C. Dietzel et al. (2020). A calcium zirconate based combined material for calcium-copper chemical looping technology. (ekstern lenke)
- Breogán Pato-Doldán; Mali Husby Rosnes; Dmitry Chernyshov et al. (2020). Carbon dioxide induced structural phase transition in metal-organic frameworks CPO-27. (ekstern lenke)
2016
- Breogán Pato-Doldán; Mali Husby Rosnes; Pascal D.C. Dietzel (2016). Shining light on the CO2 adsorption process in metal-organic framework CPO-27-M. (ekstern lenke)
- Breogán Pato-Doldán; Mali Husby Rosnes; Pascal D.C. Dietzel (2016). Shining light on the CO2 adsorption process in metal-organic framework CPO-27-M. (ekstern lenke)
- Mali Husby Rosnes; Pascal D.C. Dietzel (2016). In-depth investigations of the formation of metal-organic framework (MOF) materials. (ekstern lenke)
- Breogán Pato-Doldán; Mali Husby Rosnes; Pascal D.C. Dietzel (2016). A Comprehensive Structural Study of the CO2 Adsorption Process in the CPO-27 Family. (ekstern lenke)
- Fredrik Lundvall; Pascal D.C. Dietzel; Helmer Fjellvåg (2016). Crystal structure of dimethyl 4,4'-dimethoxybiphenyl-3,3'-dicarboxylate. (ekstern lenke)
- Mali Husby Rosnes; Pascal D.C. Dietzel (2016). In-depth investigations of the formation of functional materials. (ekstern lenke)
2015
- Andrey Bezrukov; Karl Wilhelm Törnroos; Pascal D.C. Dietzel (2015). Variation in porous coordination polymer structure due to deprotonation level of hydroxyl groups of a flexible bifunctional linker. (ekstern lenke)
- Mali Husby Rosnes; Pascal D.C. Dietzel (2015). In-depth investigations of the formation of metal-organic framework (MOF) materials. (ekstern lenke)
- Mali Husby Rosnes; Martin Opitz; Matthias Frontzek et al. (2015). Intriguing differences in hydrogen adsorption in CPO-27 materials induced by metal substitution. (ekstern lenke)
- Andrey Bezrukov; Karl Wilhelm Törnroos; Pascal D.C. Dietzel (2015). Variation in porous coordination polymer structure due to deprotonation level of hydroxyl groups of a flexible bifunctional linker. (ekstern lenke)
2013
- Pascal D.C. Dietzel (2013). MOFs: From gas adsorption to crystal structures. (ekstern lenke)
- Pascal D.C. Dietzel (2013). Structure-property relationships in coordination polymers with open metal sites. (ekstern lenke)
- Decai Yu; A. Ozqur Yazaydin; Joseph R. Lane et al. (2013). A combined experimental and quantum chemical study of CO2 adsorption in the metal-organic framework CPO-27 with different metals. (ekstern lenke)
2017
- Andrey Bezrukov; Karl Wilhelm Törnroos; Pascal D.C. Dietzel (2017). Variation of network dimensionality and adsorption properties of metal-organic frameworks based on a series of phosphine containing linkers. (ekstern lenke)
- Breogán Pato-Doldán; Mali Husby Rosnes; Pascal D.C. Dietzel (2017). An In-Depth Structural Study of the Carbon Dioxide Adsorption Process in the Porous Metal–Organic Frameworks CPO-27-M. (ekstern lenke)
- Pascal D.C. Dietzel (2017). Understanding adsorbent-adsorbate structures and structure-property relationships in metal-organic frameworks from diffraction and physisorption experiments. (ekstern lenke)
- Breogán Pato-Doldán; Mali Husby Rosnes; Pascal D.C. Dietzel (2017). A comprehensive structural study of the CO2 adsorption process in the CPO-27 family. (ekstern lenke)
- Andrey Bezrukov; Karl Wilhelm Törnroos; Pascal D.C. Dietzel (2017). New metal-organic frameworks with phosphine functional groups. (ekstern lenke)
- Mali Husby Rosnes; Denis Sheptyakov; Alexandra Franz et al. (2017). On the elusive nature of oxygen binding at coordinatively unsaturated 3d transition metal centers in metal-organic frameworks. (ekstern lenke)
- Tim Ahnfeldt; Marc Christoph Enssle; Maria del Prado Carrion-Ramirez et al. (2017). Effect of ligand substitution on breathing mode of MOFs with MIL-53 type crystal structure. (ekstern lenke)
2008
- Pascal Dietzel; Rune Esben Johnsen; R Blom et al. (2008). Structural changes and coordinatively unsaturated metal atoms on dehydration of honeycomb analogous microporous metal-organic frameworks. (ekstern lenke)
- Francesca Bonino; Sachin Chavan; Jenny Vitillo et al. (2008). Local Structure of CPO-27-Ni Metallorganic Framework upon Dehydration and Coordination of NO. (ekstern lenke)
- Pascal Daniel Croumbie Dietzel; Rune E. Johnsen; Helmer Fjellvåg et al. (2008). Adsorption properties and structure of CO2 adsorbed on open coordination sites of metal organic Framework Ni2(dhtp) from gas adsorption, IR spectroscopy and X-ray diffraction. (ekstern lenke)
2014
- Fredrik Lundvall; David Wragg; Pascal D.C. Dietzel et al. (2014). Methyl 5-iodo-2-methoxybenzoate. (ekstern lenke)
- Christian Chmelik; Alexander Mundstock; Pascal D.C. Dietzel et al. (2014). Idiosyncrasies of Co2(dhtp): In situ-annealing by methanol. (ekstern lenke)
- Fredrik Lundvall; David Wragg; Pascal D.C. Dietzel et al. (2014). 4,4′-dimethoxybiphenyl-3,3′-dicarboxylic acid. (ekstern lenke)
- Pascal D.C. Dietzel (2014). Dramatic change of interaction with hydrogen in coordination polymers with open metal sites. (ekstern lenke)
2006
- Pascal Dietzel; M Jansen (2006). Dimeric sandwich-like ion pairs in the crystal structure of tetrabutylammonium ozonide ammoniate. (ekstern lenke)
- Pascal D.C. Dietzel; Richard Blom; Helmer Fjellvåg (2006). Increased dimensionalities of zinc–diphenic acid coordination polymers by simultaneous or subsequent addition of neutral bridging ligands. (ekstern lenke)
2012
- Fredrik Lundvall; David Wragg; Pascal D.C. Dietzel et al. (2012). New MOFs based on the unexplored linker 4,4’-dimethoxy-3,3’-biphenyldicarboxylic acid. (ekstern lenke)
- Pascal D.C. Dietzel; Rune Esben Johnsen; Peter A. Georgiev et al. (2012). Structure-property relationships linking crystal structure determinations of host-guest compounds and gas adsorption experiments. (ekstern lenke)
- Marc Christoph Enssle; Pascal D.C. Dietzel; Helmer Fjellvåg (2012). Synthesis and Characterization of two new Scandium based Metal Organic Frameworks, CPO-65-Sc-NH2 and CPO-65-Sc-(NH2)2, with Amino Functionalized Linkers. (ekstern lenke)
- Pascal D.C. Dietzel; Rune Esben Johnsen; P.A. Georgiev et al. (2012). Identification of preferred adsorption sites in coordination polymers with open metal sites. (ekstern lenke)
2025
- Pascal Daniel Croumbie Dietzel (2025). Medisinsk mirakel og kjemisk magi: Dette er nobelprisvinnerne 2025. (ekstern lenke)
- Julie Brun; Amrita Panigrahi; Pascal Daniel Croumbie Dietzel (2025). Direct observation of the dehydration of a metal hydroxido cluster to a metal oxido cluster in a metal-organic framework. (ekstern lenke)
- Pascal Daniel Croumbie Dietzel (2025). Shining light on mteal-organic frameworks: From host-guest interactions to structural transformations. (ekstern lenke)
- Pascal Daniel Croumbie Dietzel (2025). How do we figure out how atoms are connected in compounds?. (ekstern lenke)
2018
- Pascal D.C. Dietzel (2018). Neues von der Bienenwabe. (ekstern lenke)
- Pascal D.C. Dietzel (2018). Metal-organic frameworks as energy materials. (ekstern lenke)
- Andrey Bezrukov; Karl Wilhelm Törnroos; Erwan Le Roux et al. (2018). Metal-organic frameworks with tridentate phosphine linkers. (ekstern lenke)
2024
- Olena Zavorotynska; Anna Cecilie Åsland; Pascal Daniel Croumbie Dietzel et al. (2024). Exploring cluster formation in Zr-MOF synthesis in situ using X-ray absorption spectroscopy. (ekstern lenke)
- Amrita Panigrahi; Pascal Daniel Croumbie Dietzel (2024). Phosphine-based Metal-organic frameworks. (ekstern lenke)